Measurements of adduct angles in the final cisplatin and oxaliplatin modeled structures, defined by atom potential types as shown in Fig. 2
| Angle | Cisplatin | Oxaliplatin |
|---|---|---|
| degrees | degrees | |
| Adduct “right” angles | ||
| N32-PT-NB1 | 89.5 | 90.5 |
| N31-PT-NB2 | 87.6 | 90.3 |
| NB1-PT-NB2 | 92.3 | 91.1 |
| N31-PT-N32 | 90.7 | 88.4 |
| Angle | Cisplatin | Oxaliplatin |
|---|---|---|
| degrees | degrees | |
| Adduct “planar” angles | ||
| NB1-PT-N31 | 177.4 | 175.9 |
| NB2-PT-N32 | 177.5 | 176.6 |
| Angle | Cisplatin | Oxaliplatin |
|---|---|---|
| degrees | degrees | |
| Base “roll” angles (relative to PT) | ||
| N*-NB1-PT | 155.0 | 156.6 |
| N*-NB2-PT | 142.3 | 143.4 |
| CB-NB1-PT (C4-N7-PT) | 158.0 | 159.5 |
| CB-NB2-PT (C4-N7-PT) | 139.9 | 143.6 |