Identification and characterization of catalytic active sites are the prerequisites for an atomic-level
understanding of the catalytic mechanism and rational design of high-performance …

Developing supported single-site catalysts is an important goal in heterogeneous catalysis
since the well-defined active sites afford opportunities for detailed mechanistic studies, …

… Loadings for the oxide supported catalysts were controlled to achieve the same Pt surface
coverage as that for the 4% Pt/Mo 2 C catalyst (1.1 atom/nm 2 ). Results from physical and …

This study reports the highly selective (more than 95%) dehydrogenation of propane to
propylene as well as the reverse hydrogenation reaction by silica-supported single-site Zn(II) …

Zr-based metal–organic frameworks (MOFs) have been shown to be excellent catalyst supports
in heterogeneous catalysis due to their exceptional stability. Additionally, their crystalline …

The OH groups on the Zr-based nodes of ultrastable UiO-66 can be metallated with V V ions
in a facile fashion to give the derivative VUiO-66. This metallated MOF exhibits high stability …

We report the synthesis, characterization, and catalytic performance for gas phase propane
dehydrogenation of single-site Co 2+ ions supported on silica. Spectroscopic …

… However, analysis of the coordination numbers (shown in Table 1 and Table 2) reveals
that the silver particle size is decreased to 4 nm as compared to 5.4 nm (from Table S1, …

We report a comparative study of isolated Fe II , iron oxide particles, and metallic nanoparticles
on silica for non-oxidative propane dehydrogenation. It was found that the most selective …

Few-atom cobalt-oxide clusters, when dispersed on a Zr-based metal–organic framework (MOF)
NU-1000, have been shown to be active for the oxidative dehydrogenation (ODH) of …