Theory of solutions in the energetic representation. I. Formulation
N Matubayasi, M Nakahara - The Journal of Chemical Physics, 2000 - pubs.aip.org
… When the grand canonical ensemble is adopted, the total number N of solvent molecules
in the system fluctuates, and N in Eq. 12 needs to be replaced by the average N u . …
in the system fluctuates, and N in Eq. 12 needs to be replaced by the average N u . …
Molecular insights on confined water in the nanochannels of self-assembled ionic liquid crystal
… The cation involves an ionic moiety of N-methyl-N,N,N-triethylammonium group, and the
terminals of the two alkyl chains are conjugated dienes. The anion is tetrafluoroborate BF 4 . …
terminals of the two alkyl chains are conjugated dienes. The anion is tetrafluoroborate BF 4 . …
Theory of solutions in the energy representation. II. Functional for the chemical potential
N Matubayasi, M Nakahara - The Journal of chemical physics, 2002 - pubs.aip.org
An approximate functional for the chemical potential of a solute in solution is presented in
the energy representation. This functional is constructed by adopting the Percus–Yevick-like …
the energy representation. This functional is constructed by adopting the Percus–Yevick-like …
Gastrophysics: Statistical thermodynamics of biomolecular denaturation and gelation from the Kirkwood-Buff theory towards the understanding of tofu
S Shimizu, R Stenner, N Matubayasi - Food Hydrocolloids, 2017 - Elsevier
… For example, Δ N u 1 in the context of protein unfolding signifies Δ N u i = N u i u − … 8) N ui
= n i v − n i n u v with the help of which Eq. (7) can be rewritten as(9) − d μ u ∗ = N u 1 d μ 1 + N …
= n i v − n i n u v with the help of which Eq. (7) can be rewritten as(9) − d μ u ∗ = N u 1 d μ 1 + N …
Theory of solutions in the energy representation. III. Treatment of the molecular flexibility
N Matubayasi, M Nakahara - The Journal of chemical physics, 2003 - pubs.aip.org
… where the equality holds only when (we( )ue( )) is a constant independent of and the
number N of solvent molecules interacting with the solute is invariant against the change in the …
number N of solvent molecules interacting with the solute is invariant against the change in the …
Structural study of supercritical water. I. Nuclear magnetic resonance spectroscopy
N Matubayasi, C Wakai, M Nakahara - The Journal of chemical physics, 1997 - pubs.aip.org
The proton chemical shift of water is measured at temperatures up to 400 C and densities of
0.19 , 0.29 , 0.41 , 0.49 , and 0.60 g / cm 3 . The magnetic susceptibility correction is made in …
0.19 , 0.29 , 0.41 , 0.49 , and 0.60 g / cm 3 . The magnetic susceptibility correction is made in …
[PDF][PDF] Protein hydration and unfolding–insights from experimental partial specific volumes and unfolded protein models
LR Murphy, N Matubayasi, VA Payne, RM Levy - Folding and Design, 1998 - cell.com
Background: The partial specific volume of a protein is an experimental quantity containing
information about solute–solvent interactions and protein hydration. We use a hydration-shell …
information about solute–solvent interactions and protein hydration. We use a hydration-shell …
Solvent Effect on Pathways and Mechanisms for d-Fructose Conversion to 5-Hydroxymethyl-2-furaldehyde: In Situ 13C NMR Study
…, M Nakahara, N Matubayasi - The Journal of Physical …, 2013 - ACS Publications
Noncatalytic reactions of d-fructose were kinetically investigated in dimethylsulfoxide (DMSO),
water, and methanol as a function of time at temperatures of 30–150 C by applying in situ …
water, and methanol as a function of time at temperatures of 30–150 C by applying in situ …
Hydrotropy: Monomer–Micelle equilibrium and minimum hydrotrope concentration
S Shimizu, N Matubayasi - The Journal of Physical Chemistry B, 2014 - ACS Publications
… Note that n 2 /n m is the fraction of the hydrotrope molecule present at the monomeric state
and that mn 3 /n m is the fraction at … We express n i in terms of T,μ 1 ,μ 2 ,N u . Under constant …
and that mn 3 /n m is the fraction at … We express n i in terms of T,μ 1 ,μ 2 ,N u . Under constant …
Energy-representation theory of solutions: Its formulation and application to soft, molecular aggregates
N Matubayasi - Bulletin of the Chemical Society of Japan, 2019 - academic.oup.com
The energy-representation theory of solutions is developed to address the dissolution of a
molecule in homogeneous fluid as well as the partitioning into such nanoscale structures as …
molecule in homogeneous fluid as well as the partitioning into such nanoscale structures as …