REVIEWChemistry, Analysis, and Biological Roles ofS-Nitrosothiols☆,☆☆
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2017, Free Radical Biology and MedicineChanges of sodium nitrate, nitrite, and N-nitrosodiethylamine during in vitro human digestion
2017, Food ChemistryCitation Excerpt :Although the exact mechanisms for reductions in nitrate, nitrite, and NDEA concentrations by pH changes during digestion are unclear, acidic conditions in the stomach (approximately pH < 1.5–2.0) may play a role in reducing the amounts of nitrate and nitrite. Anthony and Rhodes (1997) reported that possible precursors for the formation of N-nitroso compounds are nitrosothiols; these compounds form very rapidly from nitrite and thiol groups under acidic conditions and are also capable of N-nitrosation. The formation of nitrosothiols and other types of nitroso compounds are favored at low pH (such as that in the stomach) (Williams, 1983).
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Abbreviations used: NO, nitric oxideRSNO, S-nitrosothiols with R representing range of chemical entities; SNAP,S -nitroso-N-acetylpenicillamine; GSNO, S-nitrosoglutathione; NANC, nonadrenergic noncholinergic; SNP, sodium nitroprusside;
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S. MoncadaM. A. MarlettaJ. B. HibbsE. A. Higgs, Eds.