User profiles for Thomas J. Emge
Thomas J EmgeRutgers University Verified email at rutgers.edu Cited by 16554 |
A luminescent microporous metal–organic framework for the fast and reversible detection of high explosives
Detection of high explosives is attracting increasing attention owing to homeland security,
environmental and humanitarian implications.[1] 2, 4-Dinitrotoluene (DNT), an inevitable …
environmental and humanitarian implications.[1] 2, 4-Dinitrotoluene (DNT), an inevitable …
New microporous metal− organic framework demonstrating unique selectivity for detection of high explosives and aromatic compounds
… Emge - Department of Chemistry and Chemical Biology, Rutgers, The State University of
New Jersey, 610 Taylor Road, Piscataway, New Jersey 08852, United States … Akashdeep …
New Jersey, 610 Taylor Road, Piscataway, New Jersey 08852, United States … Akashdeep …
Zeolitic imidazolate frameworks for kinetic separation of propane and propene
Propane/propene separation by cryogenic distillation is one of the most energy and cost
intensive industrial processes. Adsorptive separation is a more energy-efficient alternative. …
intensive industrial processes. Adsorptive separation is a more energy-efficient alternative. …
Microporous metal–organic frameworks with high gas sorption and separation capacity
The design, synthesis, and structural characterization of two microporous metal–organic
framework structures, [M(bdc)(ted) 0.5 ]·2 DMF·0.2 H 2 O (M = Zn (1), Cu (2); H 2 bdc = 1,4‐…
framework structures, [M(bdc)(ted) 0.5 ]·2 DMF·0.2 H 2 O (M = Zn (1), Cu (2); H 2 bdc = 1,4‐…
Solution processable MOF yellow phosphor with exceptionally high quantum efficiency
An important aspect in the research and development of white light-emitting diodes (WLEDs)
is the discovery of highly efficient phosphors free of rare-earth (RE) elements. Herein we …
is the discovery of highly efficient phosphors free of rare-earth (RE) elements. Herein we …
Enhancing gas adsorption and separation capacity through ligand functionalization of microporous metal–organic framework structures
Hydroxyl‐ and amino‐ functionalized [Zn(BDC)(TED) 0.5 ]⋅2DMF⋅0.2H 2 O leads to two
new structures, [Zn(BDC‐OH)(TED) 0.5 ]⋅1.5DMF⋅0.3H 2 O and [Zn(BDC‐NH 2 )(TED) 0.5 ]⋅…
new structures, [Zn(BDC‐OH)(TED) 0.5 ]⋅1.5DMF⋅0.3H 2 O and [Zn(BDC‐NH 2 )(TED) 0.5 ]⋅…
Discovery of a small-molecule inhibitor and cellular probe of Keap1–Nrf2 protein–protein interaction
A high-throughput screen (HTS) of the MLPCN library using a homogenous fluorescence
polarization assay identified a small molecule as a first-in-class direct inhibitor of Keap1–Nrf2 …
polarization assay identified a small molecule as a first-in-class direct inhibitor of Keap1–Nrf2 …
Net Oxidative Addition of C(sp3)-F Bonds to Iridium via Initial CH Bond Activation
Carbon-fluorine bonds are the strongest known single bonds to carbon and as a consequence
can prove very hard to cleave. Alhough vinyl and aryl CF bonds can undergo oxidative …
can prove very hard to cleave. Alhough vinyl and aryl CF bonds can undergo oxidative …
A new layered metal–organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions
J Zhang, AV Biradar, S Pramanik, TJ Emge… - Chemical …, 2012 - pubs.rsc.org
A new layered MOF material [Co(Hoba)2·2H2O] (1) (H2oba = 4,4′-oxybis(benzoic acid))
has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin …
has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin …
Rational design and synthesis of highly active pincer-iridium catalysts for alkane dehydrogenation
“PCP”-pincer-ligated iridium complexes have been found to be highly effective catalysts for
the dehydrogenation of alkanes. We report a computational and experimental study of the …
the dehydrogenation of alkanes. We report a computational and experimental study of the …